Jump to main content
Jump to site search

Issue 30, 2011
Previous Article Next Article

Ionic liquids as recycling solvents for the synthesis of magnetic nanoparticles

Author affiliations

Abstract

This work describes an easy synthesis (one pot) of MFe2O4 (M = Co, Fe, Mn, and Ni) magnetic nanoparticles MNPs by the thermal decomposition of Fe(Acac)3/M(Acac)2 by using BMI·NTf2 (1-n-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide) or BMI·PF6 (1-n-butyl-3-methylimidazolium hexafluorophosphate) ionic liquids (ILs) as recycling solvents and oleylamine as the reducing and surface modifier agent. The effects of reaction temperature and reaction time on the features of the magnetic nanomaterials (size and magnetic properties) were investigated. The growth of the MNPs is easily controlled in the IL by adjusting the reaction temperature and time, as inferred from Fe3O4 MNPs obtained at 150 °C, 200 °C and 250 °C with mean diameters of 8, 10 and 15 nm, respectively. However, the thermal decomposition of Fe(Acac)3 performed in a conventional high boiling point solvent (diphenyl ether, bp 259 °C), under a similar Fe to oleylamine molar ratio used in the IL synthesis, does not follow the same growth mechanism and rendered only smaller NPs of 5 nm mean diameter. All MNPs are covered by at least one monolayer of oleylamine making them readily dispersible in non-polar solvents. Besides the influence on the nanoparticles growth, which is important for the preparation of highly crystalline MNPs, the IL was easily recycled and has been used in at least 20 successive syntheses.

Graphical abstract: Ionic liquids as recycling solvents for the synthesis of magnetic nanoparticles

Back to tab navigation

Supplementary files

Publication details

The article was received on 11 May 2011, accepted on 15 Jun 2011 and first published on 05 Jul 2011


Article type: Paper
DOI: 10.1039/C1CP21518C
Phys. Chem. Chem. Phys., 2011,13, 13558-13564

  •   Request permissions

    Ionic liquids as recycling solvents for the synthesis of magnetic nanoparticles

    F. C. C. Oliveira, F. B. Effenberger, M. H. Sousa, R. F. Jardim, P. K. Kiyohara, J. Dupont, J. C. Rubim and L. M. Rossi, Phys. Chem. Chem. Phys., 2011, 13, 13558
    DOI: 10.1039/C1CP21518C

Search articles by author

Spotlight

Advertisements