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Issue 5, 2011
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Near achiral metal–organic frameworks from conformationally flexible homochiral ligands resulted by the preferential formation of pseudo-inversion center in asymmetric unit

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Abstract

A near identical MOF from the reaction between a homochiral ligand and LaIII ion to that from racemic ligand was obtained due to the preferential formation of the pseudo-centrosymmetric arrangement in asymmetric units.

Graphical abstract: Near achiral metal–organic frameworks from conformationally flexible homochiral ligands resulted by the preferential formation of pseudo-inversion center in asymmetric unit

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Article information


Submitted
19 Jul 2010
Accepted
14 Oct 2010
First published
02 Nov 2010

CrystEngComm, 2011,13, 1277-1279
Article type
Communication

Near achiral metal–organic frameworks from conformationally flexible homochiral ligands resulted by the preferential formation of pseudo-inversion center in asymmetric unit

K. S. Jeong, B. H. Lee, Q. Li, S. B. Choi, J. Kim and N. Jeong, CrystEngComm, 2011, 13, 1277
DOI: 10.1039/C0CE00426J

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