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Issue 42, 2011
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Amino acid based chiral N-amidothioureas. Acetate anion binding induced chirality transfer

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Abstract

N-Amidothioureas generated from amine-dimethylated natural L-phenylalanine and its D-enantiomer bearing a chiral carbon that is by 2 atoms or 3 chemical bonds away from the anion binding site establish chiral communication upon acetate anion binding to the thiourea moiety.

Graphical abstract: Amino acid based chiral N-amidothioureas. Acetate anion binding induced chirality transfer

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Article information


Submitted
11 Aug 2011
Accepted
07 Sep 2011
First published
30 Sep 2011

Chem. Commun., 2011,47, 11784-11786
Article type
Communication

Amino acid based chiral N-amidothioureas. Acetate anion binding induced chirality transfer

F. Wang, W. He, J. Wang, X. Yan, Y. Zhan, Y. Ma, L. Ye, R. Yang, F. Cai, Z. Li and Y. Jiang, Chem. Commun., 2011, 47, 11784
DOI: 10.1039/C1CC14995D

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