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Issue 32, 2011
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Conversion of MT-sulfone to a trifluoromethyl group by IF5: the application of an MT-sulfone anion as a trifluoromethyl anion equivalent

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Abstract

An MT-sulfone group was converted to a trifluoromethyl group by treatment with IF5 after an alkylation reaction. Therefore, an MT-sulfone anion can be used as a trifluoromethyl anion equivalent. The formal asymmetric Michael-addition of a trifluoromethyl anion to crotonaldehyde was also performed.

Graphical abstract: Conversion of MT-sulfone to a trifluoromethyl group by IF5: the application of an MT-sulfone anion as a trifluoromethyl anion equivalent

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Article information


Submitted
01 Jun 2011
Accepted
28 Jun 2011
First published
12 Jul 2011

Chem. Commun., 2011,47, 9191-9193
Article type
Communication

Conversion of MT-sulfone to a trifluoromethyl group by IF5: the application of an MT-sulfone anion as a trifluoromethyl anion equivalent

Y. Imagawa, S. Yoshikawa, T. Fukuhara and S. Hara, Chem. Commun., 2011, 47, 9191
DOI: 10.1039/C1CC13232F

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