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Issue 30, 2011

Ethanol and wateradsorption in methanol-derived ZIF-71

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Abstract

A room temperature method for synthesizing zeolitic imidizolate framework 71 (ZIF-71) is described. The methanol-based synthesis results in >95% yields (based on Zn) and produces crystals with 70% greater surface area than reported earlier. Ethanol uptake into the ZIF compares favorably with a recent modeling-based study. Water uptake was significantly higher than model predictions.

Graphical abstract: Ethanol and water adsorption in methanol-derived ZIF-71

Supplementary files

Article information


Submitted
09 May 2011
Accepted
08 Jun 2011
First published
27 Jun 2011

Chem. Commun., 2011,47, 8667-8669
Article type
Communication

Ethanol and water adsorption in methanol-derived ZIF-71

R. P. Lively, M. E. Dose, J. A. Thompson, B. A. McCool, R. R. Chance and W. J. Koros, Chem. Commun., 2011, 47, 8667 DOI: 10.1039/C1CC12728D

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