Issue 27, 2011
From the journal:

Chemical Communications

Trans-selective hydrogermylation of alkynes promoted by methyliron and bis(germyl)hydridoiron complexes as a catalyst precursor†

Masumi Itazaki,a   Masahiro Kamitania  and  Hiroshi Nakazawa*a  

* Corresponding authors

a Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan
E-mail: nakazawa@sci.osaka-cu.ac.jp
Fax: +81-6-6605-2522
Tel: +81-6-6605-2547

Abstract

Catalytic trans-selective hydrogermylation of terminal and internal alkynes was attained by a methyliron complex, CpFe(CO)2(Me), and a bis(germyl)hydridoiron(IV) complex as a catalyst precursor. The structures of (Z)-triphenyl-(2-phenylethenyl)germane and the bis(germyl)hydridoiron(IV) complexes CpFe(CO)(H)(GeR3)2 (R = Et, Ph) were confirmed by single crystal X-ray diffraction studies.

Graphical abstract: Trans-selective hydrogermylation of alkynes promoted by methyliron and bis(germyl)hydridoiron complexes as a catalyst precursor

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Article information

DOI
https://doi.org/10.1039/C1CC12530C
Article type
Communication
Submitted
30 Apr 2011
Accepted
24 May 2011
First published
06 Jun 2011

Chem. Commun., 2011,47, 7854-7856

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Trans-selective hydrogermylation of alkynes promoted by methyliron and bis(germyl)hydridoiron complexes as a catalyst precursor

M. Itazaki, M. Kamitani and H. Nakazawa, Chem. Commun., 2011, 47, 7854 DOI: 10.1039/C1CC12530C

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