Issue 30, 2011

Unprecedented incorporation of α-emitter radioisotope 213Bi into porphyrin chelates with reference to a daughter isotope mediated assistance mechanism

Abstract

For the first time, α-emitter radioisotope 213Bi has been incorporated into porphyrin chelates, with rates matching with the short period of the radionuclide. An in situ transmetalation mechanism involving the daughter isotope 209Pb is expected to boost the 213Bi radiolabeling process.

Graphical abstract: Unprecedented incorporation of α-emitter radioisotope 213Bi into porphyrin chelates with reference to a daughter isotope mediated assistance mechanism

Supplementary files

Article information

Article type
Communication
Submitted
27 Apr 2011
Accepted
16 Jun 2011
First published
27 Jun 2011

Chem. Commun., 2011,47, 8554-8556

Unprecedented incorporation of α-emitter radioisotope 213Bi into porphyrin chelates with reference to a daughter isotope mediated assistance mechanism

S. L. Gac, B. Najjari, N. Motreff, P. R. Saec, A. Faivre-Chauvet, M. Dimanche-Boitrel, A. Morgenstern, F. Bruchertseifer, M. Lachkar and B. Boitrel, Chem. Commun., 2011, 47, 8554 DOI: 10.1039/C1CC12455B

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