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Issue 25, 2011
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Monofunctionalized pillar[5]arenes: synthesis and supramolecular structure

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Abstract

The first synthesis of a monohydroxy pillar[5]arene has been carried out, by controlling the de-O-methylation of per-methylated pillar[5]arene. Using monohydroxy pillar[5]arene as an intermediate, mono-guest-functionalized pillar[5]arene was prepared. It formed a self-inclusion complex in CDCl3 whereas in acetone-d6 dethreading of the guest moiety took place.

Graphical abstract: Monofunctionalized pillar[5]arenes: synthesis and supramolecular structure

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Publication details

The article was received on 21 Apr 2011, accepted on 06 May 2011 and first published on 24 May 2011


Article type: Communication
DOI: 10.1039/C1CC12333E
Chem. Commun., 2011,47, 7164-7166

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    Monofunctionalized pillar[5]arenes: synthesis and supramolecular structure

    T. Ogoshi, K. Demachi, K. Kitajima and T. Yamagishi, Chem. Commun., 2011, 47, 7164
    DOI: 10.1039/C1CC12333E

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