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Issue 25, 2011
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Cooperative spin transition in a lipid layer like system

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Abstract

A novel iron(II) mononuclear spin transition complex [FeL(py)2] displays an abrupt spin transition around 225 K accompanied by a very wide thermal hysteresis loop (∼50 K) that spreads out over 100 K. Crystal structure analysis in both low-spin and high-spin states reveals a lipid layer-like arrangement of the complex molecules and provides insights into the spin switching mechanism.

Graphical abstract: Cooperative spin transition in a lipid layer like system

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Publication details

The article was received on 14 Apr 2011, accepted on 09 May 2011 and first published on 23 May 2011


Article type: Communication
DOI: 10.1039/C1CC12162F
Chem. Commun., 2011,47, 7152-7154

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    Cooperative spin transition in a lipid layer like system

    S. Schlamp, B. Weber, A. D. Naik and Y. Garcia, Chem. Commun., 2011, 47, 7152
    DOI: 10.1039/C1CC12162F

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