Novel Ca-doped CePO4 supported ruthenium catalyst with superior catalytic performance for aerobic oxidation of alcohols

Yanjie Zhang; Junhu Wang; Tao Zhang

doi:10.1039/C1CC10626K

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Novel Ca-doped CePO₄ supported ruthenium catalyst with superior catalytic performance for aerobic oxidation of alcohols†

Yanjie Zhang,^a Junhu Wang*^ab and Tao Zhang*^ab

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* Corresponding authors

^a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China
E-mail: taozhang@dicp.ac.cn, wangjh@dicp.ac.cn
Fax: +86-411-84691570
Tel: +86-411-84379015

^b Mössbauer Effect Data Center, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China

Abstract

Ca-doped cerium phosphate (CeCaPO₄) has been newly developed and successfully used as catalyst support with superior ion-exchanged property and oxygen activation ability. Ru³⁺ exchanged CeCaPO₄ is identified as an efficient catalyst for aerobic oxidation of alcohols with the highest TOF (∼408 h⁻¹) reported so far on supported Ru catalysts.

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Article information

DOI: https://doi.org/10.1039/C1CC10626K
Article type: Communication
Submitted: 01 Feb 2011
Accepted: 04 Mar 2011
First published: 01 Apr 2011

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Chem. Commun., 2011,47, 5307-5309

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Novel Ca-doped CePO₄ supported ruthenium catalyst with superior catalytic performance for aerobic oxidation of alcohols

Y. Zhang, J. Wang and T. Zhang, Chem. Commun., 2011, 47, 5307 DOI: 10.1039/C1CC10626K

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