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Issue 22, 2011
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A high nuclearity mixed valence {Mn32} complex

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A mixed-valence {Mn32} complex, containing MnII, MnIII and MnIV ions, with a probable S = 5 ground state, utilizes pivalate as a capping ligand and a variety of oxo-type bridging ligands. AC susceptibility data on fresh samples suggest that the Mn32 complex is one of the largest nuclearity single molecule magnets found to date.

Graphical abstract: A high nuclearity mixed valence {Mn32} complex

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Article information

04 Jan 2011
05 Apr 2011
First published
19 Apr 2011

Chem. Commun., 2011,47, 6281-6283
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A high nuclearity mixed valence {Mn32} complex

S. K. Langley, R. A. Stott, N. F. Chilton, B. Moubaraki and K. S. Murray, Chem. Commun., 2011, 47, 6281
DOI: 10.1039/C1CC00035G

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