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Issue 13, 2011
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Conformation dynamics of non-, singly- and doubly-N-fused [28]hexaphyrins revealed by photophysical studies

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Abstract

Conformational flexibility and balance between Möbius aromatic and Hückel antiaromatic conformers in [28]hexaphyrins depend on N-fused structure and meso-aryl substituents, revealed by various spectroscopic methods. In particular, the existence of the two conformers has been confirmed for singly-N-fused [28]hexaphyrins by femtosecond time-resolved transient absorption spectroscopy.

Graphical abstract: Conformation dynamics of non-, singly- and doubly-N-fused [28]hexaphyrins revealed by photophysical studies

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Publication details

The article was received on 01 Nov 2010, accepted on 08 Feb 2011 and first published on 21 Feb 2011


Article type: Communication
DOI: 10.1039/C0CC05822J
Chem. Commun., 2011,47, 3960-3962

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    Conformation dynamics of non-, singly- and doubly-N-fused [28]hexaphyrins revealed by photophysical studies

    J. M. Lim, M. Inoue, Y. M. Sung, M. Suzuki, T. Higashino, A. Osuka and D. Kim, Chem. Commun., 2011, 47, 3960
    DOI: 10.1039/C0CC05822J

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