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Issue 11, 2011
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Direct experimental evidence for an enamine radical cation in SOMO catalysis

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Abstract

SOMO catalysis has lately obtained large interest as a new and powerful version of enantioselective organocatalysis which includes radical steps initiated by a one-electron oxidation. The intermediate enamine radical cation has been postulated, but has not been observed directly so far. This communication now reports the direct detection of this key intermediate.

Graphical abstract: Direct experimental evidence for an enamine radical cation in SOMO catalysis

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Article information


Submitted
03 Dec 2010
Accepted
19 Jan 2011
First published
01 Feb 2011

Chem. Commun., 2011,47, 3293-3295
Article type
Communication

Direct experimental evidence for an enamine radical cation in SOMO catalysis

R. Beel, S. Kobialka, M. L. Schmidt and M. Engeser, Chem. Commun., 2011, 47, 3293
DOI: 10.1039/C0CC05347C

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