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Issue 7, 2011
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Hydrogen bond induced enantioselectivity in Mn(salen)-catalysed sulfoxidaton reactions

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Abstract

A chiral Mn(salen) complex exhibiting two lactam binding sites at two rigid 1,5,7-trimethyl-3-azabicyclo[3.3.1]nonan-2-one skeletons is capable of enantioselective sulfoxidation due to spatially remote substrate hydrogen bonding.

Graphical abstract: Hydrogen bond induced enantioselectivity in Mn(salen)-catalysed sulfoxidaton reactions

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Supplementary files

Article information


Submitted
27 Oct 2010
Accepted
06 Dec 2010
First published
04 Jan 2011

Chem. Commun., 2011,47, 2137-2139
Article type
Communication

Hydrogen bond induced enantioselectivity in Mn(salen)-catalysed sulfoxidaton reactions

F. Voss, E. Herdtweck and T. Bach, Chem. Commun., 2011, 47, 2137
DOI: 10.1039/C0CC04636A

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