Issue 7, 2011
From the journal:

Chemical Communications

Hydrogen bond induced enantioselectivity in Mn(salen)-catalysed sulfoxidaton reactions†

Felix Voss,a   Eberhardt Herdtwecka  and  Thorsten Bach*a  

* Corresponding authors

a Department Chemie and Catalysis Research Center (CRC), Technische Universität München, 85747 Garching, Germany
E-mail: thorsten.bach@ch.tum.de
Fax: +49 89 28913315
Tel: +49 89 28913330

Abstract

A chiral Mn(salen) complex exhibiting two lactam binding sites at two rigid 1,5,7-trimethyl-3-azabicyclo[3.3.1]nonan-2-one skeletons is capable of enantioselective sulfoxidation due to spatially remote substrate hydrogen bonding.

Graphical abstract: Hydrogen bond induced enantioselectivity in Mn(salen)-catalysed sulfoxidaton reactions

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Article information

DOI
https://doi.org/10.1039/C0CC04636A
Article type
Communication
Submitted
27 Oct 2010
Accepted
06 Dec 2010
First published
04 Jan 2011

Chem. Commun., 2011,47, 2137-2139

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Hydrogen bond induced enantioselectivity in Mn(salen)-catalysed sulfoxidaton reactions

F. Voss, E. Herdtweck and T. Bach, Chem. Commun., 2011, 47, 2137 DOI: 10.1039/C0CC04636A

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