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Issue 38, 2011
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Optically pure bulky (hetero)arylalkyl carbinols via kinetic resolution

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Abstract

Planar chiral nucleophilic catalyst Fc-PIP was employed in the kinetic resolution of bulky (hetero)arylalkyl carbinols delivering unreacted alcohols with extremely high enantiomeric excess (>99.0% ees) in ideal conversions ranging from 50.4–56.7%.

Graphical abstract: Optically pure bulky (hetero)arylalkyl carbinols via kinetic resolution

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Article information


Submitted
27 Jul 2011
Accepted
18 Aug 2011
First published
05 Sep 2011

Chem. Commun., 2011,47, 10632-10634
Article type
Communication

Optically pure bulky (hetero)arylalkyl carbinols via kinetic resolution

B. Hu, M. Meng, J. S. Fossey, W. Mo, X. Hu and W. Deng, Chem. Commun., 2011, 47, 10632
DOI: 10.1039/C1CC14591F

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