Issue 39, 2011
From the journal:

Chemical Communications

A chiral π-stacked vinyl polymer emitting white circularly polarized light†

Kento Watanabe,a   Takeshi Sakamoto,b   Makoto Taguchi,c   Michiya Fujikic  and  Tamaki Nakano*b  

* Corresponding authors

a Graduate School of Chemistry and Chemical Sciences, Hokkaido University, Sapporo 060-8628, Japan

b Division of Biotechnology and Macromolecular Chemistry, Faculty of Engineering, Hokkaido University, Sapporo 060-8628, Japan
E-mail: nakanot@eng.hokudai.ac.jp
Fax: +81 11 706 6869
Tel: +81 11 706 6606

c Graduate School of Materials Science, Nara Institute of Science and Technology (NAIST), 8916-5 Takayama-cho, Ikoma 630-0101, Japan

Abstract

An optically active, π-stacked poly[2,7-bis(4-tert-butylphenyl)dibenzofulvene] having a preferred-handed helical conformation was synthesized by anionic polymerization. A thin film sample of the polymer exhibited broad-band white circularly polarized light (CPL) emission on photo excitation.

Graphical abstract: A chiral π-stacked vinyl polymer emitting white circularly polarized light

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Article information

DOI
https://doi.org/10.1039/C1CC13711E
Article type
Communication
Submitted
22 Jun 2011
Accepted
24 Aug 2011
First published
12 Sep 2011

Chem. Commun., 2011,47, 10996-10998

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A chiral π-stacked vinyl polymer emitting white circularly polarized light

K. Watanabe, T. Sakamoto, M. Taguchi, M. Fujiki and T. Nakano, Chem. Commun., 2011, 47, 10996 DOI: 10.1039/C1CC13711E

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