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Issue 26, 2011
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A precise hexagonal octadecanuclear Ag macrocycle with significant luminescent properties

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Abstract

The first hexagonal octadecanuclear Ag macrocycle [Ag18(TTTMB)12](NO3)18·30H2O has been hydrothermally synthesized. The outside and inner diameters of the unprecedented architecture are about 27.72(13) Å and 15.37(7) Å, respectively. This complex displays a huge increase in the intensity and lifetime of phosphorescence with decreasing temperature.

Graphical abstract: A precise hexagonal octadecanuclear Ag macrocycle with significant luminescent properties

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Article information


Submitted
14 Apr 2011
Accepted
19 May 2011
First published
31 May 2011

Chem. Commun., 2011,47, 7461-7463
Article type
Communication

A precise hexagonal octadecanuclear Ag macrocycle with significant luminescent properties

J. Jin, W. Wang, Y. Liu, H. Hou and Y. Fan, Chem. Commun., 2011, 47, 7461
DOI: 10.1039/C1CC12142A

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