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Issue 26, 2011
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Luminescence enhancement and tuning via multiple cooperative supramolecular interactions in an ion-paired multinuclear complex

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Abstract

[(3,5-(CF3)2Pz)(AgL)2]+[Ag5(3,5-(CF3)2Pz)6(CH3CN)] (L = 2-(N,N-diethylanilino-4-yl)-4,6-bis(3,5-dimethylpyrazol-1-yl)-1,3,5-triazine) shows bright and tunable emissions influenced by its supramolecular structure. Columnar stacks are assembled via cooperative interactions that include AgI⋯AgI argentophilic bonding, π⋯π stacking and AgI⋯π interactions.

Graphical abstract: Luminescence enhancement and tuning via multiple cooperative supramolecular interactions in an ion-paired multinuclear complex

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Supplementary files

Article information


Submitted
26 Feb 2011
Accepted
11 Apr 2011
First published
01 Jun 2011

Chem. Commun., 2011,47, 7434-7436
Article type
Communication

Luminescence enhancement and tuning via multiple cooperative supramolecular interactions in an ion-paired multinuclear complex

C. Yang, O. Elbjeirami, C. S. P. Gamage, H. V. R. Dias and M. A. Omary, Chem. Commun., 2011, 47, 7434
DOI: 10.1039/C1CC11161B

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