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Issue 21, 2011
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Linking [FeIII3] triangles with “double-headed”phenolic oximes

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The use of “double-headed” phenolic oximes produces a trigonal antiprismatic [FeIII3]2 cluster with an “internal cavity” filled with an additional Fe3+ ion. Magnetic measurements reveal that the competition between different exchange interactions leads to a low-spin ground multiplet weakly separated in energy from a complex pattern of low-lying excited levels.

Graphical abstract: Linking [FeIII3] triangles with “double-headed”phenolic oximes

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The article was received on 25 Feb 2011, accepted on 24 Mar 2011 and first published on 11 Apr 2011

Article type: Communication
DOI: 10.1039/C1CC11146A
Chem. Commun., 2011,47, 6018-6020

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    Linking [FeIII3] triangles with “double-headed”phenolic oximes

    K. Mason, J. Chang, E. Garlatti, A. Prescimone, S. Yoshii, H. Nojiri, J. Schnack, P. A. Tasker, S. Carretta and E. K. Brechin, Chem. Commun., 2011, 47, 6018
    DOI: 10.1039/C1CC11146A

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