Issue 8, 2011

Pyridine as trigger for chlorideisomerisation in chelated ruthenium benzylidene complexes: implications for olefinmetathesis

Abstract

The cationic pyridine adduct of a ruthenium complex bearing a chelating benzylidene and an N-heterocyclic carbene was identified as an intermediate during the activation of cis dichloro species and a novel triggering concept for olefin metathesis catalysts based on cationic species was disclosed.

Graphical abstract: Pyridine as trigger for chloride isomerisation in chelated ruthenium benzylidene complexes: implications for olefin metathesis

Supplementary files

Article information

Article type
Communication
Submitted
10 Nov 2010
Accepted
05 Jan 2011
First published
21 Jan 2011

Chem. Commun., 2011,47, 2261-2263

Pyridine as trigger for chloride isomerisation in chelated ruthenium benzylidene complexes: implications for olefin metathesis

M. Zirngast, E. Pump, A. Leitgeb, J. H. Albering and C. Slugovc, Chem. Commun., 2011, 47, 2261 DOI: 10.1039/C0CC04897F

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