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Issue 13, 2011
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The first ionothermal synthesis of a 3D ferroelectric metal–organic framework with colossal dielectric constant

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Abstract

A novel 3D (4,6)-connected topological architecture, obtained under ionothermal conditions by using 1-ethyl-3-methyl imidazolium bromide ([EMI]Br) as solvent and structure-directing agent, presents a non-centrosymmetric polar packing arrangement showing an interesting ferroelectric property.

Graphical abstract: The first ionothermal synthesis of a 3D ferroelectric metal–organic framework with colossal dielectric constant

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Publication details

The article was received on 10 Nov 2010, accepted on 25 Jan 2011 and first published on 14 Feb 2011


Article type: Communication
DOI: 10.1039/C0CC04890A
Chem. Commun., 2011,47, 3834-3836

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    The first ionothermal synthesis of a 3D ferroelectric metal–organic framework with colossal dielectric constant

    W. Ji, Q. Zhai, S. Li, Y. Jiang and M. Hu, Chem. Commun., 2011, 47, 3834
    DOI: 10.1039/C0CC04890A

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