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Issue 5, 2011
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Calix[4]arene supported clusters: a dimer of [MnIIIMnII] dimers

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Abstract

Phosphinate ligands allow for the transformation of a calix[4]arene supported [MnIII2MnII2] tetramer cluster motif into an unusual [MnIIIMnII]2 dimer of dimers; the clusters self-assemble in the crystal to form bi-layer arrays reminiscent of the typical packing of calixarene solvates.

Graphical abstract: Calix[4]arene supported clusters: a dimer of [MnIIIMnII] dimers

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Supplementary files

Article information


Submitted
17 Oct 2010
Accepted
24 Nov 2010
First published
15 Dec 2010

Chem. Commun., 2011,47, 1440-1442
Article type
Communication

Calix[4]arene supported clusters: a dimer of [MnIIIMnII] dimers

S. M. Taylor, R. D. McIntosh, C. M. Beavers, S. J. Teat, S. Piligkos, S. J. Dalgarno and E. K. Brechin, Chem. Commun., 2011, 47, 1440
DOI: 10.1039/C0CC04466K

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