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Issue 1, 2011
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Pyrene-fused subphthalocyanine

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Abstract

A pyrene-fused subphthalocyanine synthesized from a reaction of 2,7-di-tert-butyl-4,5,9,10-tetracyanopyrene and tetrafluorophthalonitrile exhibits red-shifted Q-band absorption and a unique linear arrangement in the solid state caused by a π–π stacking interaction. The concave conjugation of the SubPc moiety and the planar conjugation of the pyrene moiety enhanced its co-crystallization with C60 molecules.

Graphical abstract: Pyrene-fused subphthalocyanine

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Article information


Submitted
14 Jun 2010
Accepted
04 Aug 2010
First published
23 Aug 2010

Chem. Commun., 2011,47, 316-318
Article type
Communication

Pyrene-fused subphthalocyanine

S. Shimizu, S. Nakano, T. Hosoya and N. Kobayashi, Chem. Commun., 2011, 47, 316
DOI: 10.1039/C0CC01877E

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