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Issue 23, 2010
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Poroelastic swelling kinetics of thin hydrogel layers: comparison of theory and experiment

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Abstract

Thin poly(N-isopropylacrylamide) (PNIPAM) hydrogels were allowed to swell under two conditions: as freestanding layers and as substrate-attached layers. Through a combination of particle tracking and defocusing methods, the positions of beads embedded within the gels were monitored over time via fluorescence microscopy, providing a convenient method to track the kinetics of swelling for layers with thicknesses of the order 100 µm. These data are compared with the predictions of linear poroelastic theory, as specialized for polymer gels. This theory, along with a single set of material properties, accurately describes the observed swelling kinetics for both the freestanding and substrate-attached hydrogels. With the additional measurement of the substrate curvature induced by the swelling of the substrate-attached hydrogels, these experiments provide a simple route to completely characterize the material properties of the gel within the framework of linear poroelasticity, using only an optical microscope.

Graphical abstract: Poroelastic swelling kinetics of thin hydrogel layers: comparison of theory and experiment

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Publication details

The article was received on 26 May 2010, accepted on 12 Aug 2010 and first published on 24 Sep 2010


Article type: Paper
DOI: 10.1039/C0SM00434K
Citation: Soft Matter, 2010,6, 6004-6012
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    Poroelastic swelling kinetics of thin hydrogel layers: comparison of theory and experiment

    J. Yoon, S. Cai, Z. Suo and R. C. Hayward, Soft Matter, 2010, 6, 6004
    DOI: 10.1039/C0SM00434K

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