Issue 4, 2010
From the journal:

Chemical Science

Catalytic asymmetric allylic alkylation employing heteroatom nucleophiles: a powerful method for C–X bond formation

Barry M. Trost,*a   Ting Zhanga  and  Joshua D. Siebera  

* Corresponding authors

a Department of Chemistry, Stanford University, Stanford, CA, USA
E-mail: bmtrost@stanford.edu
Fax: +1 650-725-0002
Tel: +1 650-723-3385

Abstract

Metal catalyzed asymmetric allylic alkylation (AAA) reactions have been an extensively studied and fruitful area of research in organic chemistry. The use of heteroatom-centered nucleophiles in this reaction is a powerful method for asymmetric C–X (X = heteroatom) bond formation. This perspective summarizes developments and applications of metal catalyzed AAA reactions employing heteroatom nucleophiles.

Graphical abstract: Catalytic asymmetric allylic alkylation employing heteroatom nucleophiles: a powerful method for C–X bond formation

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Article information

DOI
https://doi.org/10.1039/C0SC00234H
Article type
Perspective
Submitted
19 Mar 2010
Accepted
01 Apr 2010
First published
18 Jun 2010

Chem. Sci., 2010,1, 427-440

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Catalytic asymmetric allylic alkylation employing heteroatom nucleophiles: a powerful method for C–X bond formation

B. M. Trost, T. Zhang and J. D. Sieber, Chem. Sci., 2010, 1, 427 DOI: 10.1039/C0SC00234H

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