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Abstract | Cited by

For the first time, the propagation rate coefficient kp of acrylonitrile has been determined in a broad temperature range in propylene carbonate solution via the pulsed laser polymerization–size exclusion chromatography technique employing a high frequency pulsed laser system. kp was determined to fit the Arrhenius relation ln(kp/L mol−1 s−1) = 14.42 − 1855K/T.

Graphical abstract: Determination of the propagation rate coefficient of acrylonitrile

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