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A third strategy for cross-dehydrogenative coupling reaction has been reported via platinum-catalyzed sp3 C–H and sp3 C–H coupling reaction in the absence of oxidant. Nitroalkanes as well as dialkyl malonate derivatives, β-keto esters and malononitrile are active participants in this coupling reaction. Both cyclic and acyclic non-activated simple ketones are good reactants in this reaction.

Graphical abstract: Platinum-catalyzed cross-dehydrogenative coupling reaction in the absence of oxidant

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