Issue 15, 2010
From the journal:

Organic & Biomolecular Chemistry

Ultrafast Grignard addition reactions in the presence of water

Gyorgyi Osztrovszky,a   Torkil Holm*a  and  Robert Madsen*a  

* Corresponding authors

a Department of Chemistry, Building 201, Technical University of Denmark, Denmark
E-mail: th@kemi.dtu.dk: rm@kemi.dtu.dk
Fax: (+45) 4593 3968

Abstract

The addition of allylmagnesium bromide and benzylmagnesium chloride to carbonyl compounds was investigated in the presence of protic reagents such as water and the rate of carbonyl addition was found to be comparable to the rate of protonation by the reagent.

Graphical abstract: Ultrafast Grignard addition reactions in the presence of water

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Article information

DOI
https://doi.org/10.1039/C0OB00170H
Article type
Communication
Submitted
25 May 2010
Accepted
09 Jun 2010
First published
25 Jun 2010

Org. Biomol. Chem., 2010,8, 3402-3404

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Ultrafast Grignard addition reactions in the presence of water

G. Osztrovszky, T. Holm and R. Madsen, Org. Biomol. Chem., 2010, 8, 3402 DOI: 10.1039/C0OB00170H

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