Unravelling the stereoselectivity in 6-exo-trig radical cyclization of α,β-unsaturated ester-tethered sugars. A tale of two stereocenters†
Abstract
A computational investigation on the origin of the stereoselectivity of 6-exo-trig radical
* Corresponding authors
a
Departamento de Química, Instituto de Ciências Exatas, Universidade Federal de Minas Gerais, UFMG, Belo Horizonte, MG, Brazil
E-mail:
mtavares@netuno.lcc.ufmg.br
b Departamento de Produtos Farmacêuticos, Faculdade de Farmácia, Universidade Federal de Minas Gerais, UFMG, Belo Horizonte, MG, Brazil
A computational investigation on the origin of the stereoselectivity of 6-exo-trig radical
M. T. de Oliveira, A. Cesar, D. H. S. Leal, M. A. F. Prado, T. H. Á. da Silva and R. J. Alves, Org. Biomol. Chem., 2010, 8, 1619 DOI: 10.1039/B923414D
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