Issue 4, 2010
From the journal:

Organic & Biomolecular Chemistry

The enantioselective total synthesis of nemotin†

Ya-Jun Jiana  and  Yikang Wu*a  

* Corresponding authors

a State Key Laboratory of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, China
E-mail: yikangwu@mail.sioc.ac.cn

Abstract

The allene–diyne natural product nemotin was synthesized for the first time through an enantioselective route with the stereogenic center at the lactone moiety derived from L-glutamic acid and the allene axis constructed from the corresponding propargylic tosylate, and the absolute configuration was thus established as (4S,5aS).

Graphical abstract: The enantioselective total synthesis of nemotin

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Article information

DOI
https://doi.org/10.1039/B923123D
Article type
Paper
Submitted
04 Nov 2009
Accepted
25 Nov 2009
First published
04 Jan 2010

Org. Biomol. Chem., 2010,8, 811-821

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The enantioselective total synthesis of nemotin

Y. Jian and Y. Wu, Org. Biomol. Chem., 2010, 8, 811 DOI: 10.1039/B923123D

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