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Abstract | Cited by

The resolution of chiral nitrones via derivatization of hydroxylamines was applied to MiPNO, a new, stable, easily prepared chiral cyclic nitrone. The application of MiPNO in totally regio- and diastereo-selective 1,3-dipolar cycloaddition reactions provides an expeditious enantioselective access to unusual γ-hydroxy α-amino acids.

Graphical abstract: MiPNO, a new chiral cyclic nitrone for enantioselective amino acid synthesis: the cycloaddition approach

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