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A general method for the synthesis of a novel class of oligomers, comprising α-hydroxy phenylphosphinic acid building blocks, is reported. A series of dimeric α-hydroxy phenylphosphinates are analyzed by a combination of NMR spectroscopy, X-ray crystallography and computational methods.

Graphical abstract: A synthesis of oligomeric α-hydroxy phenylphosphinates and a study of the conformational preferences of the dimers

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