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Issue 7, 2010
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The first supramolecular ion triplet complex

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Abstract

A neutral tritopic macrocycle 1 was obtained by condensation of a diacid dichloride 2 with a diamine 3. 1 contains three binding sites: two for anions by hydrogen bonding and one for cations by ether oxygen atoms. The selective binding of LiCl and CaCl2 has been studied by NMR and MS techniques. 1 is the first host to form a supramolecular complex with an ion triplet: 1·CaCl2.

Graphical abstract: The first supramolecular ion triplet complex

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Article information


Submitted
01 Mar 2010
Accepted
05 May 2010
First published
27 May 2010

New J. Chem., 2010,34, 1247-1250
Article type
Letter

The first supramolecular ion triplet complex

J. Eckelmann, V. Saggiomo, F. D. Sönnichsen and U. Lüning, New J. Chem., 2010, 34, 1247
DOI: 10.1039/C0NJ00160K

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