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Thermally conductive ceramic/plastic composite materials are needed in various industries for thermal management. The present work aimed at creating composite films of hexagonal boron nitride (h-BN) particles and polyimide. A thermal conductivity of 7 W m−1 K−1 was achieved at solids loading of 60 vol% with flexibility maintained.

Graphical abstract: Thermally conductive composite films of hexagonal boron nitride and polyimide with affinity-enhanced interfaces

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