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Issue 44, 2010
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On the nature of the transition metal–main group metal bond: synthesis and theoretical calculations on iridium gallyl complexes

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Abstract

The iridum–gallyl complex MeIr(PCy3)2(GaMe2)(Cl˙GaMe3) exhibits a short Ir–Ga bond length of 2.381(1)–2.389(2) Å. Theoretical calculations (ZORA BP86/TZ2P) support the presence of a Ir–Ga single bond but highlight a π orbital contribution.

Graphical abstract: On the nature of the transition metal–main group metal bond: synthesis and theoretical calculations on iridium gallyl complexes

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Article information


Submitted
19 Aug 2010
Accepted
09 Sep 2010
First published
04 Oct 2010

Dalton Trans., 2010,39, 10588-10589
Article type
Communication

On the nature of the transition metal–main group metal bond: synthesis and theoretical calculations on iridium gallyl complexes

C. J. Durango-García, J. O. C. Jiménez-Halla, M. López-Cardoso, V. Montiel-Palma, M. A. Muñoz-Hernández and G. Merino, Dalton Trans., 2010, 39, 10588
DOI: 10.1039/C0DT01071E

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