Issue 40, 2010

Unique assembly of low-dimensional viologen iodoplumbates and their improved semiconducting properties

Abstract

Two unique low-dimensional benzyl viologen iodoplumbates [Pb13I38][B′V]6 (1) and [(Pb5I14)(BV)2]n (2) were prepared from solvothermal reactions of benzyl alcohol with 4,4′-bipy, PbI2, I2 and a small amount of water in acetonitrile. The semiconducting properties of the single crystals 1 and 2 along with Zn/Cl-doped samples 2a and 2b were investigated.

Graphical abstract: Unique assembly of low-dimensional viologen iodoplumbates and their improved semiconducting properties

Supplementary files

Article information

Article type
Communication
Submitted
10 Jun 2010
Accepted
01 Sep 2010
First published
13 Sep 2010

Dalton Trans., 2010,39, 9476-9479

Unique assembly of low-dimensional viologen iodoplumbates and their improved semiconducting properties

Y. Chen, Z. Wang, Z. Yang, Z. Ren, H. Li and J. Lang, Dalton Trans., 2010, 39, 9476 DOI: 10.1039/C0DT00757A

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