Issue 41, 2010
From the journal:

Dalton Transactions

Double loading of ZnCl2 by polytopic ligands which co-extract Zn2+ and tetrachloridozincate†

Tai Lin,a   Vesna Gasperov,a   Kate J. Smith,a   Christine C. Tonga  and  Peter A. Tasker*a  

* Corresponding authors

a School of Chemistry, University of Edinburgh, West Mains Road, Edinburgh, UK
E-mail: Peter.Tasker@ed.ac.uk;
Fax: +44 131 650 6543;
Tel: +44 131 650 4706

Abstract

Combining cation- and anion-binding functionalities in a salen-type extractant leads to multiple loading of ZnCl2. Zn(II) cations are bound by the salen N2O22− donor set, and chlorozincate anions are associated with protonated pendant amine groups.

Graphical abstract: Double loading of ZnCl2 by polytopic ligands which co-extract Zn2+ and tetrachloridozincate

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Article information

DOI
https://doi.org/10.1039/C0DT00577K
Article type
Communication
Submitted
30 May 2010
Accepted
03 Sep 2010
First published
24 Sep 2010

Dalton Trans., 2010,39, 9760-9762

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Double loading of ZnCl2 by polytopic ligands which co-extract Zn2+ and tetrachloridozincate

T. Lin, V. Gasperov, K. J. Smith, C. C. Tong and P. A. Tasker, Dalton Trans., 2010, 39, 9760 DOI: 10.1039/C0DT00577K

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