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Issue 31, 2010
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A sodium ferrocenyl-phosphanidepolymer based on racemic primary aminoalkyl(bisphosphanyl)ferrocene

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Abstract

The primary aminoalkyl(bisphosphanyl)ferrocenes 2-(N,N-dimethylaminomethyl)-1,1′-bis(phosphanyl)ferrocene (3a) and N,N-dimethyl-1-[1′,2-bis(phosphanyl)ferrocenyl]ethylamine (3b) are readily available in two steps from the corresponding aminoalkylferrocenes. Deprotonation of 3a gave the first alkali metal aminoalkyl(bisphosphanido)ferrocene (4) as a one-dimensional polymer.

Graphical abstract: A sodium ferrocenyl-phosphanide polymer based on racemic primary aminoalkyl(bisphosphanyl)ferrocene

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Article information


Submitted
28 May 2010
Accepted
15 Jun 2010
First published
01 Jul 2010

Dalton Trans., 2010,39, 7217-7219
Article type
Communication

A sodium ferrocenyl-phosphanide polymer based on racemic primary aminoalkyl(bisphosphanyl)ferrocene

C. Limburg, S. Gómez-Ruiz and E. Hey-Hawkins, Dalton Trans., 2010, 39, 7217
DOI: 10.1039/C0DT00568A

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