Issue 31, 2010
From the journal:

Dalton Transactions

Conformation of N,N′-bis(3-pyridylformyl)piperazine and spontaneous formation of a saturated quadruple stranded metallohelicate†

Himansu Sekhar Sahooa  and  Dillip Kumar Chand*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Technology Madras, Chennai, India
E-mail: dillip@iitm.ac.in
Fax: +91-44-2257-4202
Tel: +91-44-2257-4224

Abstract

Ligand N,N′-bis(3-pyridylformyl)piperazine, L1, exists in syn and anti conformers in solution state almost in equal proportion. Formation of a saturated quadruple stranded helicate is observed when Pd(NO3)2 is reacted with ligand L1. In the complexed form the ligand exists in a flattened boat conformation with anti form.

Graphical abstract: Conformation of N,N′-bis(3-pyridylformyl)piperazine and spontaneous formation of a saturated quadruple stranded metallohelicate

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C0DT00337A
Article type
Communication
Submitted
20 Apr 2010
Accepted
17 Jun 2010
First published
08 Jul 2010

Dalton Trans., 2010,39, 7223-7225

Permissions

Request permissions

Conformation of N,N′-bis(3-pyridylformyl)piperazine and spontaneous formation of a saturated quadruple stranded metallohelicate

H. S. Sahoo and D. K. Chand, Dalton Trans., 2010, 39, 7223 DOI: 10.1039/C0DT00337A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements