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Issue 28, 2010
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A new chiral di-N-heterocyclic carbene (NHC) cyclophane ligand and its application in palladium enantioselective catalysis

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Abstract

This report details the synthesis and characterization of the first chiral diNHC cyclophane ligand and its palladium allyl complex. The complex was tested for 1,4-conjugate addition of phenylboronic acid to 2-cyclohexen-1-one and provides R-3-phenylcyclohexanone in 50% enantiomeric excess.

Graphical abstract: A new chiral di-N-heterocyclic carbene (NHC) cyclophane ligand and its application in palladium enantioselective catalysis

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Publication details

The article was received on 06 Apr 2010, accepted on 25 May 2010 and first published on 21 Jun 2010


Article type: Communication
DOI: 10.1039/C0DT00268B
Citation: Dalton Trans., 2010,39, 6392-6394
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    A new chiral di-N-heterocyclic carbene (NHC) cyclophane ligand and its application in palladium enantioselective catalysis

    M. S. Jeletic, I. Ghiviriga, K. A. Abboud and A. S. Veige, Dalton Trans., 2010, 39, 6392
    DOI: 10.1039/C0DT00268B

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