Issue 33, 2010
From the journal:

Dalton Transactions

Two unprecedented NLO-active coordination polymers constructed by a semi-rigid tetrahedral linker†

Li-Li Liang,a   Shi-Bin Ren,a   Jun Zhang,a   Yi-Zhi Li,a   Hong-Bin Du*a  and  Xiao-Zeng Youa  

* Corresponding authors

a State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, China
E-mail: hbdu@nju.edu.cn

Abstract

The assemblies of tetrahedral linker tetrakis[4-(carboxyphenyl)oxamethyl]methane acid (H4L) with ZnCl2 and CdBr2 yield two noncentrosymmetric, NLO-active coordination polymers [Zn4(L2)(H2O)3(DMA)]·2H2O (1) and [Cd2L(DMA)2(H2O)2] (2), respectively. 1 has an unprecedented 2-fold interpenetrating sxa topology with ferroelectric properties, while 2 has a 7-fold interpenetrating dia network.

Graphical abstract: Two unprecedented NLO-active coordination polymers constructed by a semi-rigid tetrahedral linker

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Article information

DOI
https://doi.org/10.1039/C0DT00255K
Article type
Paper
Submitted
04 Apr 2010
Accepted
03 Jun 2010
First published
23 Jul 2010

Dalton Trans., 2010,39, 7723-7726

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Two unprecedented NLO-active coordination polymers constructed by a semi-rigid tetrahedral linker

L. Liang, S. Ren, J. Zhang, Y. Li, H. Du and X. You, Dalton Trans., 2010, 39, 7723 DOI: 10.1039/C0DT00255K

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