Issue 22, 2010
From the journal:

Dalton Transactions

Periodic mesoporous Lix(Mn1/3Ni1/3Co1/3)O2 spinel†

Matthew R. Hill,*ab   Jamie Booth,a   Laure Bourgeoisc  and  Harold J. Whitfieldac  

* Corresponding authors

a CSIRO Materials Science and Engineering, Private Bag 33, Clayton South MDC, Victoria, Australia
E-mail: matthew.hill@csiro.au

b School of Chemistry, University of Melbourne, Victoria, Australia

c Monash Centre for Electron Microscopy and Department of Materials Engineering, Monash University, Victoria, Australia

Abstract

A monoclinic periodic mesoporous Lix(Mn1/3Ni1/3Co1/3)O2 spinel has been successfully prepared for the first time using a ‘two solvents’ pore infiltration methodology on hard silica templates. More commonly used synthetic techniques are not applicable to this complex material. This important battery cathode has a surface area of over 180 m2g−1 and a pore size of 5.5 nm.

Graphical abstract: Periodic mesoporous Lix(Mn1/3Ni1/3Co1/3)O2 spinel

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Article information

DOI
https://doi.org/10.1039/C005146M
Article type
Paper
Submitted
22 Mar 2010
Accepted
19 Apr 2010
First published
07 May 2010

Dalton Trans., 2010,39, 5306-5309

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Periodic mesoporous Lix(Mn1/3Ni1/3Co1/3)O2 spinel

M. R. Hill, J. Booth, L. Bourgeois and H. J. Whitfield, Dalton Trans., 2010, 39, 5306 DOI: 10.1039/C005146M

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