Issue 24, 2010

Collision induced dissociation (CID) to probe the outer sphere coordination chemistry of bis-salicylaldoximate complexes

Abstract

Ligand–ligand interactions in the outer coordination sphere make an important contribution to the effects of 3-substituents on the stabilities of anionic Cu(II) salicylaldoximato complexes [CuL(L-H)]. When substituents contain a different number of bonds the interpretation of CID tandem mass spectrometry must take into account the ability of ions to redistribute energy acquired in collisions within different numbers of vibrational modes.

Graphical abstract: Collision induced dissociation (CID) to probe the outer sphere coordination chemistry of bis-salicylaldoximate complexes

Supplementary files

Article information

Article type
Communication
Submitted
15 Feb 2010
Accepted
06 May 2010
First published
19 May 2010

Dalton Trans., 2010,39, 5614-5616

Collision induced dissociation (CID) to probe the outer sphere coordination chemistry of bis-salicylaldoximate complexes

B. D. Roach, R. S. Forgan, P. A. Tasker, R. M. Swart, J. Campbell, F. E. McAllister, A. P. Stopford and B. J. Duncombe, Dalton Trans., 2010, 39, 5614 DOI: 10.1039/C003135F

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