Sm(ii)reduction chemistry of heteroalkynes: stable adducts, reductive coupling, reductive C–C/C–N bond cleavage and trapping of the tert-butyl fragment with bulky nitriles, phosphaalkynes and isonitriles†
Abstract
Reactions of a dimetallated P
PP
C-t-Bu)2− featuring a new
N
N
C
N-t-Bu)− complex.
- This article is part of the themed collection: New horizons in organo-f-block chemistry