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Issue 19, 2010
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Self-assembly of Zn(salphen) complexes: Steric regulation, stability studies and crystallographic analysis revealing an unexpected dimeric 3,3′-t-Bu-substituted Zn(salphen) complex

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Abstract

The self-assembly features of a series of (non)symmetrical Zn(salphen) complexes have been studied in detail by X-ray crystallography, NMR and UV-vis techniques. The combined data demonstrate that the stability of these dimeric assemblies and the relative position of each monomeric unit within the dinuclear structure depend on the location and combination of the aromatic ring substituents.

Graphical abstract: Self-assembly of Zn(salphen) complexes: Steric regulation, stability studies and crystallographic analysis revealing an unexpected dimeric 3,3′-t-Bu-substituted Zn(salphen) complex

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Article information


Submitted
04 Dec 2009
Accepted
17 Mar 2010
First published
06 Apr 2010

Dalton Trans., 2010,39, 4541-4550
Article type
Paper

Self-assembly of Zn(salphen) complexes: Steric regulation, stability studies and crystallographic analysis revealing an unexpected dimeric 3,3′-t-Bu-substituted Zn(salphen) complex

M. M. Belmonte, S. J. Wezenberg, R. M. Haak, D. Anselmo, E. C. Escudero-Adán, J. Benet-Buchholz and A. W. Kleij, Dalton Trans., 2010, 39, 4541
DOI: 10.1039/B925560E

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