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Issue 20, 2010
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Ferromagnetically coupled chiral cyanide-bridged {Ni6Fe4} cages

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Abstract

Enantiomeric, ferromagnetically coupled decanuclear {Ni6Fe4} cages with adamantane-like cores were synthesized around templating tetraethylammonium cations, as shown by crystallographic analysis and CSI-MS, and their homochiral nature was confirmed by circular dichroism measurements.

Graphical abstract: Ferromagnetically coupled chiral cyanide-bridged {Ni6Fe4} cages

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Article information


Submitted
02 Dec 2009
Accepted
08 Jan 2010
First published
21 Jan 2010

Dalton Trans., 2010,39, 4730-4733
Article type
Communication

Ferromagnetically coupled chiral cyanide-bridged {Ni6Fe4} cages

T. Shiga, G. N. Newton, J. S. Mathieson, T. Tetsuka, M. Nihei, L. Cronin and H. Oshio, Dalton Trans., 2010, 39, 4730
DOI: 10.1039/B925399H

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