Calix[6]arene-picolinamide extractants for radioactive waste: effect of modification of the basicity of the pyridineN atom on the extraction efficiency and An/Ln separation

Abstract

The effect of a systematic variation of the basicity of the pyridine nitrogen atom in calix[6]arene-based picolinamide ligands on the actinide(III)/lanthanide(III) separation by solvent extraction has been investigated. The distribution coefficients for trivalent metal ions (D_M) decrease by increasing the nitric acid concentration, but for ligands (2 and 4) possessing a much less basic aromatic nitrogen atom, D_M values are considerably higher than those of ligands (1 and 5) having more basic pyridine nuclei. Also in terms of selectivity ligands 2 and 4 behave better than ligand 1 especially at nitric acid concentrations very close to those of the nuclear waste. At [H⁺] = 1 mol L⁻¹, SF_Am/Eu are still 3.23 and 1.92 for 2 and 4, respectively. A simple quantitative relationship between the efficiency of these extractants and the gas-phase basicity of suitably chosen model compounds is proposed, in order to explain the experimental extraction data, on one hand, and to orient future syntheses of ligands for An/Ln separation, on the other hand.