Issue 5, 2010
From the journal:

Dalton Transactions

Unexpected chemoselectivity in the Schiff condensation of amines with η2(C,O)- η1(O)-coordinated aldehyde†‡

Celedonio M. Álvarez,a   Raúl García-Rodríguez,a   Jose M. Martín-Alvareza  and  Daniel Miguel*a  

* Corresponding authors

a IU CINQUIMA, Química Inorgánica, Universidad de Valladolid, Valladolid, Spain
E-mail: dmsj@qi.uva.es

Abstract

The aldehyde function coordinated as η1; η2 is able to discriminate between aliphatic and aromatic amines in the Schiff condensation reaction.

Graphical abstract: Unexpected chemoselectivity in the Schiff condensation of amines with η2(C,O)- η1(O)-coordinated aldehyde

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Article information

DOI
https://doi.org/10.1039/B921892K
Article type
Communication
Submitted
19 Oct 2009
Accepted
30 Oct 2009
First published
17 Nov 2009

Dalton Trans., 2010,39, 1201-1203

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Unexpected chemoselectivity in the Schiff condensation of amines with η2(C,O)- η1(O)-coordinated aldehyde

C. M. Álvarez, R. García-Rodríguez, J. M. Martín-Alvarez and D. Miguel, Dalton Trans., 2010, 39, 1201 DOI: 10.1039/B921892K

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