Hydrothermal syntheses, crystal structures and magnetic properties of two new mixed metal copper(i) sulfites†
Abstract
Two new examples of mixed metal copper(I) sulfites, namely, Na3Mn2Cu(SO3)4(H2O)5 (1) and NaMn4Cu(SO3)5(H2O)3 (2), have been synthesized and structurally characterized. The 1D structure of 1 is built from a chain of [Mn2Cu(SO3)4]3− bridged by