Issue 32, 2010
From the journal:

Physical Chemistry Chemical Physics

Rovibrational levels of HD†

Krzysztof Pachucki*a  and  Jacek Komasa*b  

* Corresponding authors

a Institute of Theoretical Physics, University of Warsaw, Hoża 69, 00-681 Warsaw, Poland
E-mail: krp@fuw.edu.pl

b Faculty of Chemistry, A. Mickiewicz University, Grunwaldzka 6, 60-780 Poznań, Poland
E-mail: komasa@man.poznan.pl

Abstract

The dissociation energies of all rotation–vibrational states of the molecular HD in the ground electronic state are calculated to a high accuracy by including nonadiabatic, relativistic α2, and quantum electrodynamic α3 effects, with approximate treatment of small higher order α4, and finite nuclear size corrections. The obtained result for the ground molecular state of 36 405.7828(10) cm−1 is in a small disagreement with the latest most precise experimental value.

Graphical abstract: Rovibrational levels of HD

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Article information

DOI
https://doi.org/10.1039/C0CP00209G
Article type
Paper
Submitted
13 Apr 2010
Accepted
11 Jun 2010
First published
05 Aug 2010

Phys. Chem. Chem. Phys., 2010,12, 9188-9196

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Rovibrational levels of HD

K. Pachucki and J. Komasa, Phys. Chem. Chem. Phys., 2010, 12, 9188 DOI: 10.1039/C0CP00209G

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